A330-neo flights

any 5-6 hour flights for the new a330 neo?

I think most people will point you here: The Airbus A330-900neo Route Database

I do have one though, JFK-AMS with the Delta A330-900 is just outside your range. About 6:30-7 hours.

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KJFK-KSEA is one

TAP has a lot of 5-6hour flights on the neo. Ones that i recomend:
LIS-ORD
LIS-EWR
OPO-EWR and more (you can check out on their website)